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Anales de la Sociedad Científica Argentina, Vol. 242: Año 2010; No. 2 (Classic Reprint) libro .pdf Sociedad Cientifica Argentina


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Anales de la Sociedad Científica Argentina, Vol. 242: Año 2010; No. 2
We deem that there seems to be some interesting undiscovered possibilities on the hydrides possi ble for B, C, N, 0 and F, and particularly for N Thus we must point out that the hydrides of B have been investigated and elucidated originally by Stock [2] and after him many other authors have made significant contributions [3 We understand that the hydrides of B differ from those of C, N, 0 and F in that they exhibit in some cases exceptions to covalent, electron - pair, 2 - center bonds, in the form of electron deficient, 3 - center bonds, and that there are innumerable hydrides of B, like the innumerable hydrides of C, which in some cases display resonance effects in their hydroboron structures as suggested by Pauling and the hydrides of C are innumerable and they universally possess Lewis octet, covalent, electron - pair, 2-center bonds, with rare exceptions in which a hydrocarbon has perhaps C atoms in strained geometries which may possess coordination numbers different than 3 or 4, they are successfully described.
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